A physical explanation for relativistic length contraction?

My last posts were all about a possible physical interpretation of the quantum-mechanical wavefunction. To be precise, we have been interpreting the wavefunction as a gravitational wave. In this interpretation, the real and imaginary component of the wavefunction get a physical dimension: force per unit mass (newton per kg). The inspiration here was the structural similarity between Coulomb’s and Newton’s force laws. They both look alike: it’s just that one gives us a force per unit charge (newton per coulomb), while the other gives us a force per unit mass.

So… Well… Many nice things came out of this – and I wrote about that at length – but last night I was thinking this interpretation may also offer an explanation of relativistic length contraction. Before we get there, let us re-visit our hypothesis.

The geometry of the wavefunction

The elementary wavefunction is written as:

ψ = a·ei(E·t − px)/ħa·cos(px/ħ – E∙t/ħ) + i·a·sin(px/ħ – E∙t/ħ)

Nature should not care about our conventions for measuring the phase angle clockwise or counterclockwise and, therefore, the ψ = a·ei[E·t − px]/ħ function may also be permitted. We know that cos(θ) = cos(θ) and sinθ = sin(θ), so we can write:    

ψ = a·ei(E·t − p∙x)/ħa·cos(E∙t/ħ – px/ħ) + i·a·sin(E∙t/ħ – px/ħ)

= a·cos(px/ħ – E∙t/ħ) i·a·sin(px/ħ – E∙t/ħ)

The vectors p and x are the the momentum and position vector respectively: p = (px, py, pz) and x = (x, y, z). However, if we assume there is no uncertainty about p – not about the direction nor the magnitude – then we may choose an x-axis which reflects the direction of p. As such, x = (x, y, z) reduces to (x, 0, 0), and px/ħ reduces to p∙x/ħ. This amounts to saying our particle is traveling along the x-axis or, if p = 0, that our particle is located somewhere on the x-axis. Hence, the analysis is one-dimensional only.

The geometry of the elementary wavefunction is illustrated below. The x-axis is the direction of propagation, and the y- and z-axes represent the real and imaginary part of the wavefunction respectively.

Note that, when applying the right-hand rule for the axes, the vertical axis is the y-axis, not the z-axis. Hence, we may associate the vertical axis with the cosine component, and the horizontal axis with the sine component. You can check this as follows: if the origin is the (x, t) = (0, 0) point, then cos(θ) = cos(0) = 1 and sin(θ) = sin(0) = 0. This is reflected in both illustrations, which show a left- and a right-handed wave respectively. We speculated this should correspond to the two possible values for the quantum-mechanical spin of the wave: +ħ/2 or −ħ/2. The cosine and sine components for the left-handed wave are shown below. Needless to say, the cosine and sine function are the same, except for a phase difference of π/2: sin(θ) = cos(θ − π/2).

circular polarizaton with components

As for the wave velocity, and its direction of propagation, we know that the (phase) velocity of any wave F(kx – ωt) is given by vp = ω/k = (E/ħ)/(p/ħ) = E/p. Of course, the momentum might also be in the negative x-direction, in which case k would be equal to -p and, therefore, we would get a negative phase velocity: vp = ω/k = E/p.

The de Broglie relations

E/ħ = ω gives the frequency in time (expressed in radians per second), while p/ħ = k gives us the wavenumber, or the frequency in space (expressed in radians per meter). Of course, we may write: f = ω/2π  and λ = 2π/k, which gives us the two de Broglie relations:

  1. E = ħ∙ω = h∙f
  2. p = ħ∙k = h/λ

The frequency in time is easy to interpret. The wavefunction of a particle with more energy, or more mass, will have a higher density in time than a particle with less energy.

In contrast, the second de Broglie relation is somewhat harder to interpret. According to the p = h/λ relation, the wavelength is inversely proportional to the momentum: λ = h/p. The velocity of a photon, or a (theoretical) particle with zero rest mass (m0 = 0), is c and, therefore, we find that p = mvv = mcc = m∙c (all of the energy is kinetic). Hence, we can write: p∙c = m∙c2 = E, which we may also write as: E/p = c. Hence, for a particle with zero rest mass, the wavelength can be written as:

λ = h/p = hc/E = h/mc

However, this is a limiting situation – applicable to photons only. Real-life matter-particles should have some mass[1] and, therefore, their velocity will never be c.[2]

Hence, if p goes to zero, then the wavelength becomes infinitely long: if p → 0 then λ → ∞. How should we interpret this inverse proportionality between λ and p? To answer this question, let us first see what this wavelength λ actually represents.

If we look at the ψ = a·cos(p∙x/ħ – E∙t/ħ) – i·a·sin(p∙x/ħ – E∙t/ħ) once more, and if we write p∙x/ħ as Δ, then we can look at p∙x/ħ as a phase factor, and so we will be interested to know for what x this phase factor Δ = p∙x/ħ will be equal to 2π. So we write:

Δ =p∙x/ħ = 2π ⇔ x = 2π∙ħ/p = h/p = λ

So now we get a meaningful interpretation for that wavelength. It is the distance between the crests (or the troughs) of the wave, so to speak, as illustrated below. Of course, this two-dimensional wave has no real crests or troughs: we measure crests and troughs against the y-axis here. Hence, our definition depend on the frame of reference.

wavelength

Now we know what λ actually represents for our one-dimensional elementary wavefunction. Now, the time that is needed for one cycle is equal to T = 1/f = 2π·(ħ/E). Hence, we can now calculate the wave velocity:

v = λ/T = (h/p)/[2π·(ħ/E)] = E/p

Unsurprisingly, we just get the phase velocity that we had calculated already: v = vp = E/p. The question remains: what if p is zero? What if we are looking at some particle at rest? It is an intriguing question: we get an infinitely long wavelength, and an infinite wave velocity.

Now, re-writing the v = E/p as v = m∙c2/m∙vg  = cg, in which βg is the relative classical velocity[3] of our particle βg = vg/c) tells us that the phase velocities will effectively be superluminal (βg  < 1 so 1/ βg > 1), but what if βg approaches zero? The conclusion seems unavoidable: for a particle at rest, we only have a frequency in time, as the wavefunction reduces to:

ψ = a·e−i·E·t/ħ = a·cos(E∙t/ħ) – i·a·sin(E∙t/ħ)

How should we interpret this?

A physical interpretation of relativistic length contraction?

In my previous posts, we argued that the oscillations of the wavefunction pack energy. Because the energy of our particle is finite, the wave train cannot be infinitely long. If we assume some definite number of oscillations, then the string of oscillations will be shorter as λ decreases. Hence, the physical interpretation of the wavefunction that is offered here may explain relativistic length contraction.

🙂

Yep. Think about it. 🙂

[1] Even neutrinos have some (rest) mass. This was first confirmed by the US-Japan Super-Kamiokande collaboration in 1998. Neutrinos oscillate between three so-called flavors: electron neutrinos, muon neutrinos and tau neutrinos. Recent data suggests that the sum of their masses is less than a millionth of the rest mass of an electron. Hence, they propagate at speeds that are very near to the speed of light.

[2] Using the Lorentz factor (γ), we can write the relativistically correct formula for the kinetic energy as KE = E − E0 = mvc2 − m0c2 = m0γc2 − m0c2 = m0c2(γ − 1). As v approaches c, γ approaches infinity and, therefore, the kinetic energy would become infinite as well.

[3] Because our particle will be represented by a wave packet, i.e. a superimposition of elementary waves with different E and p, the classical velocity of the particle becomes the group velocity of the wave, which is why we denote it by vg.

The wavefunction and relativity

When reading about quantum theory, and wave mechanics, you will often encounter the rather enigmatic statement that the Schrödinger equation is not relativistically correct. What does that mean?

In my previous post on the wavefunction and relativity, I boldly claimed that relativity theory had been around for quite a while when the young Comte Louis de Broglie wrote his short groundbreaking PhD thesis, back in 1924. Moreover, it is more than likely that he suggested the θ = ω∙t – kx = (E∙t – px)/ħ formula for the argument of the wavefunction exactly because relativity theory had already established the invariance of the four-vector product pμxμ = E∙t – px = pμ‘xμ‘ = E’∙t’ – p’x’. [Note that Planck’s constant, as a physical constant, should obviously not depend on the reference frame either. Hence, if the E∙t – px product is invariant, so is (E∙t – px)/ħ.] However, I didn’t prove that, and I didn’t relate it to Schrödinger’s equation. Hence, let’s explore the matter somewhat further here.

I don’t want to do the academic thing, of course – and that is to prove the invariance of the four-vector dot product. If you want such proof, let me just give you a link to some course material that does just that. Here, I will just summarize the conclusions of such course material:

  1. Four-vector dot products – like xμxμ = xμ2, pμpμ = pμ2, the spacetime interval s= (Δr)– Δt2, or our pμxμ product here – are invariant under a Lorentz transformation (aka as a Lorentz boost). To be formally correct, I should write xμxμ, pμpμ, and pμxμ, because the product multiplies a row vector with a column vector, which is what the sub- and superscript indicate.
  2. Four-vector dot products are referred to as Lorentz scalars.
  3. When derivatives are involved, we must use the so-called four-gradient, which is denoted by  or μ and defined as:

 = μ = (∂/∂t, –) = (∂/∂t, –∂/∂x, –∂/∂y, –∂/∂z)

Applying the four-gradient vector operator to the wavefunction, we get:

μψ= (∂ψ/∂t, –ψ) = (∂ψ/∂t, –∂ψ/∂x, –∂ψ/∂y, –∂ψ/∂z)

We wrote about that in the context of electromagnetic theory (see, for instance, my post on the relativistic transformation of fields), so I won’t dwell on it here. Note, however, that that’s the weak spot in Schrödinger’s equation: it’s good, but not good enough. However, in the context in which it’s being used – i.e. to calculate electron orbitals – the approximation works just fine, so you shouldn’t worry about it. The point to remember is that the wavefunction itself is relativistically correct. 🙂

Of course, it is always good to work through a simple example, so let’s do that here. Let me first remind you of that transformation we presented a couple of times already, and that’s how to calculate the argument of the wavefunction in the reference frame of the particle itself, i.e. the inertial frame. It goes like this: when measuring all variables in Planck units, the physical constants ħ and c are numerically equal to one, then we can then re-write the argument of the wavefunction as follows:

  1. ħ = 1 ⇒ θ = (E∙t – p∙x)/ħ = E∙t – p∙x = Ev∙t − (mvv)∙x
  2. E= E0/√(1−v2) and m= m0/√(1−v2)  ⇒ θ = [E0/√(1−v2)]∙t – [m0v/√(1−v2)]∙x
  3. c = 1 ⇒ m0 = E⇒ θ = [E0/√(1−v2)]∙t – [E0v/√(1−v2)]∙x = E0∙(t − v∙x)/√(1−v2)

⇔ θ = E0∙t’ = E’·t’ with t’ = (t − v∙x)/√(1−v2)

The t’ in the θ = E0∙t’ expression is, obviously, the proper time as measured in the inertial reference frame. Needless to say, is the relative velocity, which is usually denoted by β. Note that this derivation uses the numerical m0 = E0 identity, which emerges when using natural time and distance units (c = 1). However, while mass and energy are equivalent, they are different physical concepts and, hence, they still have different physical dimensions. It is interesting to spell out what happens with the dimensions here:

  • The dimension of Evt and/or E0∙t’ is (N∙m)∙s, i.e. the dimension of (physical) action.
  • The dimension of the (mvv)∙x term must be the same, but how is that possible? Despite us using natural units – so the value of is now some number between 0 and 1 – velocity is what it is: velocity. Hence, its dimension is m/s. Hence, the dimension of the mvv∙x term is kg∙m = (N∙s2/m)∙(m/s)∙m = N∙m∙s.
  • Hence, the dimension of the [E0v/√(1−v2)]∙x term only makes sense if we remember the m2/s2 dimension of the c2 factor in the E = m∙c2 equivalence relation. We write: [E0v∙x] = [E0]∙[v]∙[x] = [(N∙m)∙(s2/m2)]∙(m/s)∙m = N∙m∙s. In short, when doing the mv = Ev and/or m0 = E0 substitution, we should not get rid of the physical 1/c2 dimension.

That should be clear enough. Let’s now do the example. The rest energy of an electron, expressed in Planck units, EeP = Ee/EP = (0.511×10eV)/(1.22×1028 eV) = 4.181×10−23. That is a very tiny fraction. However, the numerical value of the Planck time unit is even smaller: about 5.4×10−44 seconds. Hence, as a frequency is expressed as the number of cycles (or, as an angular frequency, as the number of radians) per time unit, the natural frequency of the wavefunction of the electron is 4.181×10−23 rad per Planck time unit, so that’s a frequency in the order of [4.181×10−23/(2π)]/(5.4×10−44 s) ≈ 1×1020 cycles per second (or hertz). The relevant calculations are given hereunder.

Electron
Rest energy (in joule) 8.1871E-14
Planck energy (in joule) 1.9562E+09
Rest energy in Planck units 4.1853E-23
Frequency in cycles per second 1.2356E+20

Because of these rather incredible numbers (like 10–31 or 1020), the calculations are not always very obvious, but the logic is clear enough: a higher rest mass increases the (angular) frequency of the real and imaginary part of the wavefunction, and gives them a much higher density in spacetime. How does a frequency like 1.235×1020 Hz compare to, say, the frequency of gamma rays. The answer may surprise you: they are of the same order, as is their energy! 🙂 However, their nature, as a wave ,is obviously very different: gamma rays are an electromagnetic wave, so they involve an E and B vector, rather than the two components of the matter-wave. As an energy propagation mechanism, they are structurally similar, though, as I showed in my previous post.

Now, the typical speed of an electron is given by of the fine-structure constant (α), which is (also) equal to the  is the (relative) speed of an electron (for the many interpretations of the fine-structure constant, see my post on it). So we write:

α = β = v/c

More importantly, we can use this formula to calculate it, which is done hereunder. As you can see, while the typical electron speed is quite impressive (about 2,188 km per second), it is only a fraction of the speed of light and, therefore, the Lorentz factor is still equal to one for all practical purposes. Therefore, its speed adds hardly anything to its energy.

 

Fine-structure constant 0.007297353
Typical speed of the electron (m/s) 2.1877E+06
Typical speed of the electron (km/s) 2,188 km/s
Lorentz factor (γ) 1.0000266267

But I admit it does have momentum now and, hence, the p∙x term in the θ = E∙t – p∙x comes into play. What is its momentum? That’s calculated below. Remember we calculate all in Planck units here!

Electron energy moving at alpha (in Planck units) 4.1854E-23
Electron mass moving at alpha (in Planck units) 4.1854E-23
Planck momentum (p = m·v = m·α ) 3.0542E-25

The momentum is tiny, but it’s real. Also note the increase in its energy. Now, when substituting x for x = v·t, we get the following formula for the argument of our wavefunction:

θ = E·t – p·x = E·t − p·v·t = mv·t − mv·v·v·t = mv·(1 − v2)·t

Now, how does that compare to our θ = θ = E0∙t’ = E’·t’ expression? Well… The value of the two coefficients is calculated below. You can, effectively, see it hardly matters.

mv·(1 − v2) 4.1852E-23
Rest energy in Planck units 4.1853E-23

With that, we are finally ready to use the non-relativistic Schrödinger equation in a non-relativistic way, i.e. we can start calculating electron orbitals with it now, which is what we did in one of my previous posts, but I will re-visit that post soon – and provide some extra commentary! 🙂

Amplitudes, wavefunctions and relativity – or the de Broglie equation re-visited

My previous posts were rather technical and, hence, I thought I’d re-visit a topic on which I’ve written before – but represent it from another angle: the de Broglie equation. You know it by heart: it associates a wavelength (λ) with the momentum (p) of a particle: λ = h/p. It’s a simple relationship: the wavelength and the momentum are inversely proportional, and the constant of proportionality is Planck’s constant. It’s an equation you’ll find in all of the popular accounts of quantum mechanics. However, I am of the opinion that the equation may actually not help novices to understand what quantum mechanics is all about—at least not in an initial approach.

One barrier to a proper understanding is that the de Broglie relation is always being presented as the twin of the Planck-Einstein relation for photons, which relates the energy (E) of a photon to its frequency (n): E = h∙ν = ħ∙ω [i]. It’s only natural, then, to try to relate the two equations, as momentum and energy are obviously related one to anotyher. But how exactly? What energy concept should we use? Potential energy? Kinetic energy? Should we include the equivalent energy of the rest mass?

One quickly gets into trouble here. For example, one can try the kinetic energy, K.E. = m∙v2/2 and use the definition of momentum (p = m∙v) to write E = p2/(2m), and then relate the frequency ν to the wavelength λ using the general rule that the traveling speed of a wave is equal to the product of its wavelength and its frequency (v = λ∙ν). But if E = p2/(2m) and ν = v/λ, we get:

p2/(2m) = h∙v/λ ⇔ λ = 2∙h/p

So that is almost right, but not quite: that factor 2 should not be there. In fact, it’s easy to see that we’d get de Broglie’s equation if we’d use E = m∙v2 rather than E = m∙v2/2. But E = m∙v2? How could we possibly justify the use of that formula? There’s something weird here—something deep, but I will probably die before I figure out exactly what. 🙂

Note: I should make a reference to the argument of the wavefunction here: E·t −p·x. [The argument of the wavefunction has a 1/ħ factor in front, but we assume we measure both E as well as p in units of ħ here.]  So that’s an invariant quantity, i.e. it doesn’t change under a relativistic transformation of the reference frame. Now, if we measure time and distance in equivalent units, so = 1, then we can show that E/p = 1/v. [Remember: if c would not be one, we’d write: E·β = p·c, with β = v/c, i.e. the relative velocity of our particle, as measured as a ratio of the speed of light.] As E·t − p·x, is an invariant quantity, it’s some constant that’s characteristic of the particle. But x and t change as the clock is tick. Well… Yes. But if we believe the particle is somehow real, and its velocity is v, then the ratio of the real position x and the time t should be equal to = x/t. Hence, for these very special positions x, i.e. the real position of the particle, we can equate E·t −p·x to E·t −p·v·t = E·t −m·v·v·t = (E − m∙v2)·t. So there we have the m∙v2 factor. There   must be something very deep about it, but, as mentioned above, I will probably die before I figure out exactly what. 🙂

The second problem is the interpretation of λ. Of course, λ is just a length in space, which we can relate to the spatial frequency or wavenumber k = 2π/λ [ii]. And, of course, the frequency and the wavelength are, once again, related through the traveling speed of the wave: v = λ∙ν. But then, when you think about it, it’s actually not that simple: the wavefunction of a particle is much more complicated. For starters, you should think of it as a wave packet, or wavetrain, i.e. a composite wave: a sum of a potentially infinite number of elementary waves. So we do not have a simple periodic phenomenon here: we need to distinguish the so-called group velocity from the phase velocity, and we’re also talking a complex-valued wavefunction, so it’s all quite different from what we’re used to.

But back to the energy concept. We have Einstein’s E = m∙c2 = m0∙γ∙c2 equation, of course, from which the relativistically correct momentum-energy relationship can be derived [iii]:

Capture

Ep is the energy of a particle with momentum p, and the relationship establishes a one-to-one relationship between the energy and the momentum of a particle [iv], with the rest mass (or rest energy) E02 = m0∙c2 appearing as a constant (the rest mass does not depend on the reference frame – per definition). However, you can try this formula too, but it will not give you the de Broglie relation. In short, it doesn’t help us in terms of understanding what the de Broglie relation is all about.

So how did this young nobleman, back in 1924, as he was writing his PhD thesis, get this λ = h/p or – using the wavenumber – the k = p/ħ equation?

Well… The relativity theory had been around for quite a while and, amongst other things (including the momentum-energy relationship above), it had also established the invariance of the four-vector product pμxμ = E∙t – px = pμ‘xμ‘ = E’∙t’ – p’x’.

Now, any regular sinusoidal wave is associated with a phase θ = ωt – kx, and then quantum theory had associated a complex-valued wavefunction Ψ(θ) = Ψ(ωt – kx) with a particle, and so the young count, Louis de Broglie, saw the mathematical similarity between the E∙t – px and ωt – kx expressions, and then just took the bold step of substituting ω and k for E/ħ and p/ħ respectively in the Ψ(ωt – kx) function. That’s it really: as the laws of physics should look the same, regardless of our frame of reference, he realized the argument of the wavefunction needed to be some invariant quantity, and so that’s what he gets through this substitution.

Of course, the substitution makes sense: it has to. To show why, let’s consider the limiting situation of a particle with zero momentum – so it’s at rest, really – but assuming that the probability of finding it at some point in space, at some point of time is equally distributed over space and time. So we have the rather nonsensical but oft-used wavefunction:

Ψ(θ) = Ψ(x, t) = a·eiθ = a·ei(ωt – k∙x)

Taking the absolute square of this yields a constant probability equal to aindeed. The equation is non-sensical or – to put it more politely – a limiting case only because it assumes perfect knowledge about the particle’s momentum p (we said it was zero, exactly) and, hence, about its energy. So we don’t need to worry about any Δ here: Δp = ΔE = 0 and Ep = E0. As mentioned, we know that doesn’t make much sense, and that a particle in free space will actually be represented by a wave train with a group velocity v (i.e. the classical speed of the particle) and a phase velocity, and so that’s where the modeling of uncertainty comes in, but let’s just go along with the example now. [Note that, while p = 0, that does not imply that E0 is equal to zero. Indeed, there’s energy in the rest mass and possibly potential energy too!]

Now, if we substitute ω and k for E/ħ and p/ħ respectively – note that we did away with the bold-face k and x, so we’ve reduced the analysis to one dimension (x) only – we get:

Ψ(θ) = Ψ(x, t) = a·eiθ = a·ei(E0t – p∙x)/ħ a·ei(E0/ħ)t

What this means is that the phase θ = (E0/ħ)·t does not depend on x: it only varies in time. Hence, the diagram below – don’t look at the x’ and t’ right now: that’s another reference frame that we’ll introduce in a moment – shows equal-phase lines parallel to the x-axis and, because of the θ = (E0/ħ)·t equation, they’re equally spaced in time, i.e. in the t-coordinate.

phase

Of course, a particle at rest in one reference frame – let’s say S – will appear to be moving in another – which we’ll denote as S’, so we have the primed coordinates x’ and t’, which are related to the x and t by the Lorentz transformation rules. It’s easy to see that the points of equal phase have a different spacing along the t’-axis, so the frequency in time must be different. Indeed, we’ll write that frequency as ω’ = Ep‘/ħ in the S’ reference frame.

Likewise, we see that the phase now does vary in space, so the probability amplitude does vary in space now, as the particle’s momentum in the primed reference frame is no longer zero: if we write it as p’, then we can write that θ = (E0/ħ)·t = (Ep‘/ħ)·t − (p/ħ)∙x = (Ep‘/ħ)·t − (p/ħ)∙x. Therefore, our wavefunction becomes:

Ψ(θ) = Ψ(x, t) = a·eiθ = a·ei(E0/ħ)t = Ψ(x’, t’) = a·ei(Ep‘·t’ − p’∙x’)/ħ 

We could introduce yet another reference frame, and we’d get similar results. The point is: the k in our Ψ(θ) = Ψ(x, t) = a·eiθ = a·ei(ωt – k∙x) equation is, effectively, equal to k = p/ħ, and that identity holds in any reference frame.

Now, none of what I wrote above actually proves the de Broglie relation: it merely explains it. When everything is said and done, the de Broglie relation is a hypothesis, but it is an important one—and it does fit into the overall quantum-mechanical or wave-mechanical approach, that physicists take for granted nowadays.

So that’s it, really. I have nothing more to write but I should, perhaps, just remind you about what I said about a ‘particle wave’: we should look at it as some composite wave. Indeed, there will be uncertainty, and the uncertainty in E implies a frequency range Δω = Δ(E/ħ) = ΔE/ħ. Likewise, the momentum will be unknown, and so we’ll have a spread in the wavenumber k as well. We write: Δk = Δ(p/ħ) = Δp/ħ. We can try to reduce this uncertainty, but the Uncertainty Principle gives us the limits: the Δp·Δx and/or the ΔE·Δt products cannot be smaller than ħ/2.

So we’ll have a potentially infinite number of waves with slightly different values for ω and k, whose sum may be visualized as a complex-valued traveling wavetrain, like the lump below.

Photon wave

All of the component waves necessarily need to travel at the same speed, and this speed, which is the ratio of ω and k, will be equal to the so-called phase velocity of the wave (vp), which we can calculate as v= ω/k = (E/ħ)/(p/ħ) = E/p = (m·c2)/(m·v) = c2/v. This speed is superluminal (c2/v = c/β, with β = v/c < 1), but that is not in contradiction with special relativity because the phase velocity carries no ‘signal’ or ‘information’. As for the group velocity (vg), we can effectively see that this is equal to the classical velocity of our ‘particle’ by noting that:

v= dω/dk = d(E/ħ)/d(p/ħ) = dE/dp = d[(p2/(2m)]/dp = p/m = v.

You may think there’s some cheating here, as we equate E with the kinetic energy only. You’re right: the total energy should also include potential energy and rest energy, so E is a sum, but then rest energy and potential energy are treated as constants and, hence, it’s only the kinetic energy that matters when taking the derivative with respect to p, and so that’s why get the result we get, which makes perfect sense.

I wanted this to be a very short post, and so I will effectively end it here. I hope you enjoyed it. It actually sets the stage for a more interesting discussion, and that’s a discussion on how a change in potential energy effectively changes the phase and, hence, the amplitude. But so that’s for next time. I also need to devote a separate post on a discussion of the wave-mechanical framework in general, with a particular focus on the math behind. So… Well… Yes, the next posts are likely to be somewhat more technical again. :-/

[i] I should make a note on notations here, and also insert some definitions. I will denote a frequency by ν (nu), rather than by f, so as to not cause confusion with any function f. A frequency is expressed in cycles per second, while the angular frequency ω is expressed in radians per second. One cycle covers 2π radians and, therefore, we can write: ν = ω/2π. Hence, h∙ν = h∙ω/2π = ħ∙ω. Both ν as well as ω measure the time-rate of change of the phase, as opposed to k, i.e. the spatial frequency of the wave, which depends on the speed of wave. I will also use the symbol v for the speed of a wave, although that is hugely confusing, because I will also use it to denote the classical velocity of the particle. However, I find the conventional use of the symbol of c even more confusing, because this symbol is also used for the speed of light, and the speed of a wave is not necessarily equal to the speed of light. In fact, both the group as well as the phase velocity of a particle wave are very different from the speed of light. The speed of a wave and the speed of light only coincide for electromagnetic waves and, even then, it should be noted that photons also have amplitudes to travel faster or slower than the speed of light.

[ii] Note that the de Broglie relation can be re-written as k = p/ħ, with ħ = h/2π. Indeed, λ = 2π/k and, hence, we get: λ = h/p ⇔ 2π/k = h/p ⇔ p = ħ∙k ⇔ k = p/ħ.

[iii] One gets the equation by equating m to m = m0γ (γ is the Lorentz factor) in the E2 = (mc2)2 equation, and re-arranging.

[iv] Note that this energy formula does not include any potential energy: it is (equivalent) rest mass plus kinetic energy only.